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题名: Shielding membrane surface carboxyl groups by covalent-binding graphene oxide to improve anti-fouling property and the simultaneous promotion of flux
作者: Han, Jing-Long; Xia, Xue; Tao, Yu; Yun, Hui; Hou, Ya-Nan; Zhao, Chang-Wei; Luo, Qin; Cheng, Hao-Yi; Wang, Ai-Jie
刊名: WATER RESEARCH
出版日期: 2016-10-01
卷号: 102, 期号:0, 页码:619-628
关键词: Membrane modification ; Combined membrane fouling ; Membrane filtration ; Wastewater secondary effluent treatment ; Volume charge density ; Zeta potential
DOI: 10.1016/j.watres.2016.06.032
部门归属: 中国科学院环境生物技术重点实验室
英文摘要: Graphene oxide (GO) is an excellent material for membrane surface modification. However, little is known about how and to what extent surface functional groups change after GO modification influence membrane anti-fouling properties. Carboxyl is an inherent functional group on polyamide or other similar membranes. Multivalent cations in wastewater secondary effluent can bridge with carboxyls on membrane surfaces and organic foulants, resulting in serious membrane fouling. In this study, carboxyls of a polydopamine (pDA)/1,3,5-benzenetricarbonyl trichloride (TMC) active layer are shielded by covalently-bound GO. The process is mediated by N-(3-dimethylaminopropyl)-N'-ethylcarbodiimide (EDC)/N-hydroxysuccinimide (NHS). For GO containing low quantities of carboxyls, X-ray photoelectron spectroscopy (XPS) and zeta potential analyzer test results reveal that the carboxyl density decreased by 52.3% compare to the pDA/TMC membrane after GO modification. Fouling experiments shows that the flux only slightly declines in the GO functionalized membrane (19.0%), compared with the pDA/TMC membrane (36.0%) after fouling. In addition, during GO modification process the pDA/TMC active layer also become harder and thinner with the aid of EDC/NHS. So the pure water permeability increases from 56.3 +/- 18.2 to 103.7 +/- 12.0 LMH/MPa. Our results provide new insights for membrane modification work in water treatment and other related fields. (C) 2016 Elsevier Ltd. All rights reserved.
收录类别: SCI
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内容类型: 期刊论文
URI标识: http://ir.rcees.ac.cn/handle/311016/36145
Appears in Collections:中国科学院环境生物技术重点实验室_期刊论文

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Recommended Citation:
Han, Jing-Long,Xia, Xue,Tao, Yu,et al. Shielding membrane surface carboxyl groups by covalent-binding graphene oxide to improve anti-fouling property and the simultaneous promotion of flux[J]. WATER RESEARCH,2016,102(0):619-628.
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