| An efficient cis-reduction of alkyne to alkene in the presence of a vinyl iodide: stereoselective synthesis of the C22-C31 fragment of leiodolide A | |
| Zhang, Xing; Liu, Jun; Sun, Xue; Du, Yuguo; Liu, J | |
| 2013 | |
| Source Publication | TETRAHEDRON
 |
| Volume | 69Issue:5Pages:1553-1558 |
| Abstract | Rapid and efficient reduction of allcyne bond in the presence of a vinyl iodide is established using freshly prepared Brown's P2-Ni as the catalyst, affording the semihydrogenated alkene products in good to excellent yields (73-91%). Based on this new method, a stereoselective synthesis of the key C22-C31 fragment of marine macrolide leiodolide A has been developed. (C) 2012 Elsevier Ltd. All rights reserved. |
| Department | 环境化学与生态毒理学国家重点实验室 |
| Indexed By | SCI |
| WOS ID | WOS:000315064600018 |
| Citation statistics | |
| Document Type | 期刊论文 |
| Identifier | http://ir.rcees.ac.cn/handle/311016/7530 |
| Collection | 环境化学与生态毒理学国家重点实验室 |
| Corresponding Author | Liu, J |
| Recommended Citation GB/T 7714 | Zhang, Xing,Liu, Jun,Sun, Xue,et al. An efficient cis-reduction of alkyne to alkene in the presence of a vinyl iodide: stereoselective synthesis of the C22-C31 fragment of leiodolide A[J]. TETRAHEDRON,2013,69(5):1553-1558. |
| APA | Zhang, Xing,Liu, Jun,Sun, Xue,Du, Yuguo,&Liu, J.(2013).An efficient cis-reduction of alkyne to alkene in the presence of a vinyl iodide: stereoselective synthesis of the C22-C31 fragment of leiodolide A.TETRAHEDRON,69(5),1553-1558. |
| MLA | Zhang, Xing,et al."An efficient cis-reduction of alkyne to alkene in the presence of a vinyl iodide: stereoselective synthesis of the C22-C31 fragment of leiodolide A".TETRAHEDRON 69.5(2013):1553-1558. |
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