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Total Synthesis of (-)-Orthodiffenes A and C
Liu, Jun; Liu, Yi; Zhang, Xing; Zhang, Chaoli; Gao, Yangguang; Wang, LinLin; Du, Yuguo
AbstractThe efficient and concise synthesis of (-)-orthodiffenes A and C has been accomplished for the first time in eight steps from readily available chiral synthons, D-mannose and D-ethyl lactate. Our work confirmed the complete structure of orthodiffenes A and C, including their absolute stereochemistry. The key steps of our total synthesis involved cis-fused tetrahydrofuran cyclization, one-pot deprotection-lactonization, and intramolecular benzoyl migration according to a biosynthetic hypothesis of orthodiffenes.
WOS IDWOS:000311190200031
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Cited Times:14[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
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GB/T 7714
Liu, Jun,Liu, Yi,Zhang, Xing,et al. Total Synthesis of (-)-Orthodiffenes A and C[J]. JOURNAL OF ORGANIC CHEMISTRY,2012,77(21):9718-9723.
APA Liu, Jun.,Liu, Yi.,Zhang, Xing.,Zhang, Chaoli.,Gao, Yangguang.,...&Du, Yuguo.(2012).Total Synthesis of (-)-Orthodiffenes A and C.JOURNAL OF ORGANIC CHEMISTRY,77(21),9718-9723.
MLA Liu, Jun,et al."Total Synthesis of (-)-Orthodiffenes A and C".JOURNAL OF ORGANIC CHEMISTRY 77.21(2012):9718-9723.
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