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Factors governing formation of todorokite at atmospheric pressure
Cui, HJ; Feng, XH; Liu, F; Tan, WF; He, JZ
2005
Source PublicationSCIENCE IN CHINA SERIES D-EARTH SCIENCES
Volume48Issue:10Pages:1678-1689
AbstractTodorokite commonly occurs in Earth surface environments. The factors governing formation of todorokite, such as reaction temperature, metal ions, dissolved O-2 and pH, were investigated in this paper. Results showed that the forming rate of todorokite and its crystallinity decreased with falling reaction temperature, and the effect of temperature was more significant than that of other parameters. Nature of metal ions in the interlayer of buserite precursor and the structure of the buserite precursor obviously affected buserite transformation into todorokite. Weak bonding between the metal ions and MnO6 layer of buserite was favorable to todorokite formation. The rate of todorokite formation was promoted at a lower temperature with appropriate bubbling of O-2. The pH in the system slightly influenced the todorokite formation, and todorokite could also be formed in a weak alkali medium or in a slightly acidic medium. Aged buserite precursor more easily form todorokite than the unaged one.
Department土壤环境科学实验室
KeywordTodorokite Buserite Manganese Oxide Mineral Atmospheric Pressure Transformation
WOS Research AreaGeology
Citation statistics
Document Type期刊论文
Identifierhttps://ir.rcees.ac.cn/handle/311016/23344
Collection土壤环境科学实验室
Recommended Citation
GB/T 7714
Cui, HJ,Feng, XH,Liu, F,et al. Factors governing formation of todorokite at atmospheric pressure[J]. SCIENCE IN CHINA SERIES D-EARTH SCIENCES,2005,48(10):1678-1689.
APA Cui, HJ,Feng, XH,Liu, F,Tan, WF,&He, JZ.(2005).Factors governing formation of todorokite at atmospheric pressure.SCIENCE IN CHINA SERIES D-EARTH SCIENCES,48(10),1678-1689.
MLA Cui, HJ,et al."Factors governing formation of todorokite at atmospheric pressure".SCIENCE IN CHINA SERIES D-EARTH SCIENCES 48.10(2005):1678-1689.
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