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Total synthesis of quercetin 3-sophorotrioside
Du, YG; Wei, GH; Linhardt, RJ
2004
Source PublicationJOURNAL OF ORGANIC CHEMISTRY
Volume69Issue:6Pages:2206-2209
Abstract5,7-Dihydroxy-3-[beta-D-glucopyranosyl-(1-->2)-beta-D-glucopyranosyl-(1-->2)-beta-D-glucopyranosyl]-2-(3,4-dihydroxy- phenyl)-4H-1-benzopyran-4-one (quercetin 3-sophorotrioside), a flavonol triglycoside, isolated from Pisum sativurn shoots and showing protective effects on liver injury induced by chemicals, was synthesized for the first time. The target compound was successfully synthesized in eight linear steps and in 39% overall yield through a combination of phasetransfer-catalyzed (PTC) quercetin C-3 glycosylation and silver triflate (AgOTf) promoted carbohydrate chain elongation using both sugar bromide and trichloroacetimidate donors.
Department环境化学与生态毒理学国家重点实验室
WOS Research AreaChemistry
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Document Type期刊论文
Identifierhttps://ir.rcees.ac.cn/handle/311016/23492
Collection环境化学与生态毒理学国家重点实验室
Recommended Citation
GB/T 7714
Du, YG,Wei, GH,Linhardt, RJ. Total synthesis of quercetin 3-sophorotrioside[J]. JOURNAL OF ORGANIC CHEMISTRY,2004,69(6):2206-2209.
APA Du, YG,Wei, GH,&Linhardt, RJ.(2004).Total synthesis of quercetin 3-sophorotrioside.JOURNAL OF ORGANIC CHEMISTRY,69(6),2206-2209.
MLA Du, YG,et al."Total synthesis of quercetin 3-sophorotrioside".JOURNAL OF ORGANIC CHEMISTRY 69.6(2004):2206-2209.
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