Simultaneous As(III) and Cd removal from copper smelting wastewater using granular TiO2 columns | |
Yan, Li; Huang, Yuying; Cui, Jinli; Jing, Chuanyong | |
2015 | |
Source Publication | WATER RESEARCH
![]() |
Volume | 68Pages:572-579 |
Abstract | Remediation of metallurgical industry wastewater has presented a great environmental challenge for decades. In this study, a complete remediation technology was proposed for simultaneous As(III) and Cd adsorptive removal, adsorbent regeneration, and recovery of As and Cd. Using three granular TiO2 columns in series, As(III) and Cd in the raw water at 2590 +/- 295 and 12 +/- 2 mg/L, respectively, could be reduced to 0.16 +/- 0.11 and 0.0133 +/- 0.0134 mg/L, well below the wastewater discharge limit. Spent TiO2 media could be regenerated using H2SO4 and NaOH, and the regenerated adsorbent could be re-used for at least 10 treatment cycles and 770 bed volumes with no decrease in its adsorption capacity. Remediation of 1 L wastewater generated 0.89-1.5 g solid residue which could be used as an intermediate for the As and Cd chemical refinement. The waste solution can be further treated after mixing with raw water to adjust the raw pH from 1.4 to 7. This adsorption, regeneration, and reuse process provides an innovative technology for metallurgical industry wastewater remediation that is promising for practical application. (C) 2014 Elsevier Ltd. All rights reserved. |
Department | 环境化学与生态毒理学国家重点实验室 |
Keyword | Metallurgical Wastewater Granular Tio2 Fixed-bed Columns Adsorbent Regeneration On-line Treatment Process |
WOS Research Area | Engineering, Environmental ; Environmental Sciences ; Water Resources |
Citation statistics | |
Document Type | 期刊论文 |
Identifier | https://ir.rcees.ac.cn/handle/311016/32662 |
Collection | 环境化学与生态毒理学国家重点实验室 |
Recommended Citation GB/T 7714 | Yan, Li,Huang, Yuying,Cui, Jinli,et al. Simultaneous As(III) and Cd removal from copper smelting wastewater using granular TiO2 columns[J]. WATER RESEARCH,2015,68:572-579. |
APA | Yan, Li,Huang, Yuying,Cui, Jinli,&Jing, Chuanyong.(2015).Simultaneous As(III) and Cd removal from copper smelting wastewater using granular TiO2 columns.WATER RESEARCH,68,572-579. |
MLA | Yan, Li,et al."Simultaneous As(III) and Cd removal from copper smelting wastewater using granular TiO2 columns".WATER RESEARCH 68(2015):572-579. |
Files in This Item: | Download All | |||||
File Name/Size | DocType | Version | Access | License | ||
Simultaneous As(III)(1625KB) | 期刊论文 | 作者接受稿 | 开放获取 | CC BY-NC-SA | View Download |
Items in the repository are protected by copyright, with all rights reserved, unless otherwise indicated.
Edit Comment