| Water-based synthesis of zeolitic imidazolate framework-8 with high morphology level at room temperature | |
| Jian, Meipeng; Liu, Bao; Liu, Ruiping; Qu, Jiuhui; Wang, Huanting; Zhang, Xiwang | |
| 2015 | |
| Source Publication | RSC ADVANCES
 |
| Volume | 5Issue:60Pages:48433-48441 |
| Abstract | In this study, the synthesis of zeolitic imidazole framework (ZIF-8) in water was systematically studied using 6 zinc sources (Zn(OAc)(2), ZnSO4, Zn(NO3)(2), ZnCl2, ZnBr2, ZnI2), respectively, under different conditions at room temperature without using any additives. It was found that Zn(OAc)(2) is the best precursor and the resultant ZIF-8 particles have the best quality with rhombic dodecahedron morphology. The concentration of 2-methylimidazole (Hmim), molar ratio Hmim/Zn and water content all have significant impacts on the morphology, particle size, and crystallinity of ZIF-8. Further result analysis reveals that 3 key reactions are involved in the ZIF-8 formation which needs five steps in ZIF-8 structural evolution. This study provides a deep understanding of the crystallization process of ZIF-8 particles in a waterbased system. |
| Department | 环境化学与生态毒理学国家重点实验室 |
| WOS Research Area | Chemistry, Multidisciplinary |
| Citation statistics | |
| Document Type | 期刊论文 |
| Identifier | https://ir.rcees.ac.cn/handle/311016/32698 |
| Collection | 环境化学与生态毒理学国家重点实验室 |
| Recommended Citation GB/T 7714 | Jian, Meipeng,Liu, Bao,Liu, Ruiping,et al. Water-based synthesis of zeolitic imidazolate framework-8 with high morphology level at room temperature[J]. RSC ADVANCES,2015,5(60):48433-48441. |
| APA | Jian, Meipeng,Liu, Bao,Liu, Ruiping,Qu, Jiuhui,Wang, Huanting,&Zhang, Xiwang.(2015).Water-based synthesis of zeolitic imidazolate framework-8 with high morphology level at room temperature.RSC ADVANCES,5(60),48433-48441. |
| MLA | Jian, Meipeng,et al."Water-based synthesis of zeolitic imidazolate framework-8 with high morphology level at room temperature".RSC ADVANCES 5.60(2015):48433-48441. |
| Files in This Item: | Download All | |||||
| File Name/Size | DocType | Version | Access | License | ||
| Water-based synthesi（1941KB） | 期刊论文 | 作者接受稿 | 开放获取 | CC BY-NC-SA | View Download | |
Items in the repository are protected by copyright, with all rights reserved, unless otherwise indicated.
Edit Comment