RCEES OpenIR  > 环境化学与生态毒理学国家重点实验室
Thermal decomposition tandem mass spectrometry for rapid detection of tetrabromobisphenol A bis(allyl ether) in soils
Liu, Huan; Gao, Wei1,2; Tian, Yong; Wang, Yongmei; Liu, Aifeng; Zhang, Jianqing3; Jiang, Yousheng3; Zhao, Zongshan; Cai, Yaqi4; Jiang, Guibin4
2019-08-01
Source PublicationTALANTA
ISSN0039-9140
Volume200Pages:373-377
AbstractRapidly and sensitively determining trace levels of contaminants with poor ionization in complex matrices is a great challenge for mass spectrometry analysis. In this work, a thermal decomposition tandem mass spectrometry (TD-MS/MS) method is developed for fast detecting tetrabromobisphenol A bis(allyl ether) (TBBPA-BAE) in soils. Typically, TBBPA-BAE solution in a capillary is decomposed and ionized under heating, then sprayed into the mass spectrometer for MS analysis. Upon optimization, one high abundant ion of m/z 542.75 from TBBPA-BAE by debromination is detected during heating process. By collision-induced dissociation, the ion is fragmented to release the characteristic ion of m/z 501.72, which is used as the target quantitative ion. Each test can be finished within 3 min. A linear range of 0.1-100 mu g L-1 limit of detection (LOD, S/N = 3, n = 9) of 0.015 mu g L-1, and relative standard deviation of 8.6% (c = 0.1 mu g L-1, n = 5) are achieved. The fast and sensitive performance of the developed method for analyzing TBBPA-BAE in soils presents its great potential for studying trace levels of TBBPA derivative contaminants.
Department环境化学与生态毒理学国家重点实验室
KeywordThermal decomposition Tandem mass spectrometry Tetrabromobisphenol A bis(allyl ether) Rapid quantitative analysis
Document Type期刊论文
Identifierhttps://ir.rcees.ac.cn/handle/311016/42607
Collection环境化学与生态毒理学国家重点实验室
Affiliation1.Chinese Acad Sci, Qingdao Inst Bioenergy & Bioproc Technol, CAS Key Lab Biobased Mat, Qingdao 266101, Shandong, Peoples R China
2.Northeastern Univ, Res Ctr Analyt Sci, Coll Sci, Shenyang 110819, Liaoning, Peoples R China
3.Northeastern Univ, Dept Chem, Coll Sci, Shenyang 110819, Liaoning, Peoples R China
4.Shenzhen Ctr Dis Control & Prevent, Shenzhen 518055, Peoples R China
5.Chinese Acad Sci, Res Ctr Ecoenvironm Sci, State Key Lab Environm Chem & Ecotoxicol, Beijing 100085, Peoples R China
Recommended Citation
GB/T 7714
Liu, Huan,Gao, Wei,Tian, Yong,et al. Thermal decomposition tandem mass spectrometry for rapid detection of tetrabromobisphenol A bis(allyl ether) in soils[J]. TALANTA,2019,200:373-377.
APA Liu, Huan.,Gao, Wei.,Tian, Yong.,Wang, Yongmei.,Liu, Aifeng.,...&Jiang, Guibin.(2019).Thermal decomposition tandem mass spectrometry for rapid detection of tetrabromobisphenol A bis(allyl ether) in soils.TALANTA,200,373-377.
MLA Liu, Huan,et al."Thermal decomposition tandem mass spectrometry for rapid detection of tetrabromobisphenol A bis(allyl ether) in soils".TALANTA 200(2019):373-377.
Files in This Item: Download All
File Name/Size DocType Version Access License
Thermal decompositio(1472KB)期刊论文出版稿开放获取CC BY-NC-SAView Download
Related Services
Recommend this item
Bookmark
Usage statistics
Export to Endnote
Google Scholar
Similar articles in Google Scholar
[Liu, Huan]'s Articles
[Gao, Wei]'s Articles
[Tian, Yong]'s Articles
Baidu academic
Similar articles in Baidu academic
[Liu, Huan]'s Articles
[Gao, Wei]'s Articles
[Tian, Yong]'s Articles
Bing Scholar
Similar articles in Bing Scholar
[Liu, Huan]'s Articles
[Gao, Wei]'s Articles
[Tian, Yong]'s Articles
Terms of Use
No data!
Social Bookmark/Share
File name: Thermal decomposition tandem mass spectrometry for rapid detection of tetrabromobisphenol A bis(allyl ether) in soils.pdf
Format: Adobe PDF
All comments (0)
No comment.
 

Items in the repository are protected by copyright, with all rights reserved, unless otherwise indicated.