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Volatile organic compounds emission in the rubber products manufacturing processes; Volatile organic compounds emission in the rubber products manufacturing processes.pdf
Huang, Haimei; Wang, Zhangwei; Dai, Chunhao; Guo, Jia; Zhang, Xiaoshan
2022-09-01
Source PublicationENVIRONMENTAL RESEARCH
ISSN0013-9351
Volume212Issue:0Pages:113485
AbstractVolatile organic compounds (VOCs) emission from rubber products manufacture processes, mixing, shaping and vulcanization were investigated in four rubber products factories in China. The source emission air was passively sampled by pre-vacuumized stainless steel canister and analyzed by gas chromatography-mass spectrometryflame ionization detection (GC/MS-FID). The species profile of 107 VOCs in the emission processes were obtained. We calculated the photochemical ozone formation potential (OFP) and carcinogenic risk (CR) of the VOCs for each manufacture process. The results showed that mixing process mainly released dichloromethane (14.53%), carbon disulfide (CS2) (6.88%), styrene (5.72%), 4-methyl-2-pentanone (5.22%) and naphthalene (3.69%) for solvents used and raw rubber degradation in the process. The C6-C8 alkanes, especially heptane and isomers of heptane (44.71%), were dominated in shaping process. The major species released from vulcanization process were carbon disulfide (29.72%), naphthalene (8.17%), acetone (7.73%) and dichloromethane (4.26%). VOCs emitted from vulcanization process had the highest OFP, which contributed by naphthalene, m/p-xylene, o-xylene and carbon disulfide. VOCs emission from mixing process had the highest CR, and 1,2-dibromoethane, 1,2-dichlorethane and 1,3-butadiene were the main contributors to CR. We also estimated the total VOCs emissions into the atmosphere from tires manufacturing in China, which were 7.58 x 105 t in 2018 and contributed about 9% of total industry processes VOCs emissions.
Department城市与区域生态国家重点实验室 ; 城市与区域生态国家重点实验室
KeywordPEARL RIVER DELTA GROUND-LEVEL OZONE GAS-CHROMATOGRAPHY SOURCE PROFILES COMPOUNDS VOCS CHINA IDENTIFICATION FACILITIES SPECIATION PYROLYSIS
Document Type期刊论文
Identifierhttps://ir.rcees.ac.cn/handle/311016/47375
Collection城市与区域生态国家重点实验室
Corresponding AuthorWang, Zhangwei
Affiliation1.Chinese Acad Sci, Res Ctr Ecoenvironm Sci, Beijing 100085, Peoples R China
2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China
3.Hunan Agr Univ, Changsha 430106, Peoples R China
Recommended Citation
GB/T 7714
Huang, Haimei,Wang, Zhangwei,Dai, Chunhao,et al. Volatile organic compounds emission in the rubber products manufacturing processes, Volatile organic compounds emission in the rubber products manufacturing processes.pdf[J]. ENVIRONMENTAL RESEARCH,2022,212(0):113485.
APA Huang, Haimei,Wang, Zhangwei,Dai, Chunhao,Guo, Jia,&Zhang, Xiaoshan.(2022).Volatile organic compounds emission in the rubber products manufacturing processes.ENVIRONMENTAL RESEARCH,212(0),113485.
MLA Huang, Haimei,et al."Volatile organic compounds emission in the rubber products manufacturing processes".ENVIRONMENTAL RESEARCH 212.0(2022):113485.
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