| Green synthesis of graphite-based photo-Fenton nanocatalyst from waste tar via a self-reduction and solvent-free strategy | |
Li, Dong; Yang, Tianxue; Liu, Zhengang ; Xia, Yu; Chen, Zeliang; Yang, Shengshu; Gai, Chao; Bhatnagar, Amit; Ng, Yun Hau; Ok, Yong Sik
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| 2022-06-10 | |
| Source Publication | SCIENCE OF THE TOTAL ENVIRONMENT
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| ISSN | 0048-9697 |
| Volume | 824Issue:0Pages:153772 |
| Abstract | Thermochemical conversion of biomass yields large quantities of tar as a by-product, which is a potential precursor for the synthesis of renewable carbon-based functional materials. In this study, high-performance photo-Fenton catalyst of graphite-carbon-supported iron nanoparticles was synthesized using a self-reduction and solvent-free approach. The results showed that the tar-derived catalyst had unique properties including a defect-rich graphitic structure, high surface area, and an abundant porous structure resulting from the inherent properties of biomass tar. The iron nanoparticles were highly dispersed within the prepared catalysts and were stably anchored on the carbonaceous surface by the FeC bond. The prepared nanocatalyst showed the highest decomposition constant (91.87 x 10(-3) min(-1)) for 20 mM H2O2, and 40 mg/L RhB can be completely degraded within 2 h under catalyst dosage of 1 g/L and H2O2 addition of 20 mM. The degradation mechanism under the photo-Fenton catalyst/H2O2/light system included the heterogeneous Fenton reaction of iron nanoparticles and photo-Fenton reaction of iron oxide, and the efficient RhB degradation was mainly ascribed to the heterogeneous Fenton reaction. In addition, recycling and leaching tests demonstrated that the photo-Fenton catalyst had excellent reusability and stability, where only 7.3% catalytic reactivity was reduced after five cycles. This work provided a green, sustainable, and facile approach for synthesizing photo-Fenton catalysts by value-added utilization of tar wastes. |
| Department | 固体废弃物处理与资源化实验室 ; 固体废弃物处理与资源化实验室 |
| Keyword | PHASE-TRANSFORMATION CATALYTIC-OXIDATION HYDROGEN-PEROXIDE IRON-OXIDE CARBON DEGRADATION MECHANISM GRAPHENE ALPHA-FE2O3 PERFORMANCE |
| Document Type | 期刊论文 |
| Identifier | https://ir.rcees.ac.cn/handle/311016/47435 |
| Collection | 固体废弃物处理与资源化实验室 |
| Affiliation | 1.Chinese Acad Sci, Ecoenvironm Sci Res Ctr, 18 Shuangqing Rd, Beijing 100085, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China 3.Chinese Res Inst Environm Sci, State Key Lab Environm Criteria & Risk Assessment, Beijing 100012, Peoples R China 4.LUT Univ, Dept Separat Sci, LUT Sch Engn Sci, Sammonkatu 12, FI-50130 Mikkeli, Finland 5.City Univ Hong Kong, Sch Energy & Environm, Kowloon, Hong Kong, Peoples R China |
| Recommended Citation GB/T 7714 | Li, Dong,Yang, Tianxue,Liu, Zhengang,et al. Green synthesis of graphite-based photo-Fenton nanocatalyst from waste tar via a self-reduction and solvent-free strategy[J]. SCIENCE OF THE TOTAL ENVIRONMENT,2022,824(0):153772. |
| APA | Li, Dong.,Yang, Tianxue.,Liu, Zhengang.,Xia, Yu.,Chen, Zeliang.,...&Ok, Yong Sik.(2022).Green synthesis of graphite-based photo-Fenton nanocatalyst from waste tar via a self-reduction and solvent-free strategy.SCIENCE OF THE TOTAL ENVIRONMENT,824(0),153772. |
| MLA | Li, Dong,et al."Green synthesis of graphite-based photo-Fenton nanocatalyst from waste tar via a self-reduction and solvent-free strategy".SCIENCE OF THE TOTAL ENVIRONMENT 824.0(2022):153772. |
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| Green synthesis of g（2990KB） | 期刊论文 | 出版稿 | 开放获取 | CC BY-NC-SA | View Application Full Text | |
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