| The bimetallic effect promotes the activity of Rh in catalyzed selective hydrogenation of phenol | |
Li, Shiwei ; Zhao, Huachao; Ran, Wei; Liu, Jingfu; Liu, Rui
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| 2022-09-15 | |
| Source Publication | CHEMICAL COMMUNICATIONS
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| ISSN | 1359-7345 |
| Volume | 58Issue:74Pages:10357-10360 |
| Abstract | Au@RhPd ultrathin nanowires are designed as a highly reactive and selective catalyst for the hydrogenation of phenol under ambient conditions. Au NWs modulate the electronic state of Rh atoms to enhance the adsorption of phenol and desorption of cyclohexanone. Pd works as a cocatalyst to activate H-2 to H* and spillover to Rh sites. This new catalyst shows a turnover frequency of up to 560 h(-1) for a wide spectrum of phenols with >80% selectivity toward cyclohexanones. |
| Department | 环境化学与生态毒理学国家重点实验室 ; 环境化学与生态毒理学国家重点实验室 |
| Keyword | GOLD |
| Document Type | 期刊论文 |
| Identifier | https://ir.rcees.ac.cn/handle/311016/47628 |
| Collection | 环境化学与生态毒理学国家重点实验室 |
| Corresponding Author | Liu, Rui |
| Affiliation | 1.Chinese Acad Sci, Res Ctr Ecoenvironm Sci, State Key Lab Environm Chem & Ecotoxicol, Beijing 100085, Peoples R China 2.Univ Chinese Acad Sci, Coll Resources & Environm, Beijing 100049, Peoples R China 3.UCAS, Hangzhou Inst Adv Study, Sch Environm, Hangzhou 310024, Peoples R China |
| Recommended Citation GB/T 7714 | Li, Shiwei,Zhao, Huachao,Ran, Wei,et al. The bimetallic effect promotes the activity of Rh in catalyzed selective hydrogenation of phenol[J]. CHEMICAL COMMUNICATIONS,2022,58(74):10357-10360. |
| APA | Li, Shiwei,Zhao, Huachao,Ran, Wei,Liu, Jingfu,&Liu, Rui.(2022).The bimetallic effect promotes the activity of Rh in catalyzed selective hydrogenation of phenol.CHEMICAL COMMUNICATIONS,58(74),10357-10360. |
| MLA | Li, Shiwei,et al."The bimetallic effect promotes the activity of Rh in catalyzed selective hydrogenation of phenol".CHEMICAL COMMUNICATIONS 58.74(2022):10357-10360. |
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| The bimetallic effec（960KB） | 期刊论文 | 出版稿 | 开放获取 | CC BY-NC-SA | View Download | |
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