KMS of Research Center for Eco-Environmental Sciences， CAS
| Passive sampling hydrophilic and hydrophobic bisphenol analogues using hydrophilic-lipophilic balance sorbent-embedded cellulose acetate membrane in surface waters | |
Gao, Xiaozhong; Li, Juying; Xu, Yiping ; Zhou, Qingxiang; Ma, Mei; Wang, Zijian
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| 2022-09-15 | |
| Source Publication | SCIENCE OF THE TOTAL ENVIRONMENT
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| ISSN | 0048-9697 |
| Volume | 839Issue:0Pages:156239 |
| Abstract | Bisphenol analogues (BPs) are ubiquitous emerging contaminants in water environments and have wide polarity ranges (1.65 < log K-ow < 7.2). Integrated passive sampling strategy rarely contains hydrophilic and hydrophobic organics simultaneously, while the method has good application perspective in monitoring organic contaminants. This work evaluated passive sampling performance for fifteen BPs in a newly developed passive sampler, i.e., hydrophilic-lipophilic balance sorbent-embedded cellulose acetate membrane (HECAM). In the dynamic accumulation experiments, both hydrophilic and hydrophobic BPs (including moderately hydrophilic BPs) well followed first-order kinetic uptake in the HECAMs. The estimated uptake rate constants, elimination rate constants, and equilibrium partition coefficients for BPs ranged from 4.4 L g(-1) d(-1) to 14.7 L g(-1) d(-1), 0.22 d(-1) to 0.72 d(-1), and 3.99 to 4.64, respectively. The kinetic parameters for BPs in HECAM show limited correlations to log Kow values, which the rule differs from traditional passive sampler. In the study of elimination kinetics, three deuterium labeled compounds showed incomplete elimination in HECAM and did not follow first-order isotropic exchange kinetics. Dual sorption mechanisms including both adsorption and partition were found for chemicals in HECAM, which the partitioned part could release to water and the adsorbed part could not easily release to water from HECAM. As a result, performance reference compounds (PRCs) calibration may be inapplicable to HLB sorbent-based passive sampler. The field deployment of HECAM in coastal waters of Guangdong, China resulted in the detection of eleven BPs, which indicated that the waters have been polluted by various BPs. Finally, monitoring strategy of simultaneous passive sampling hydrophobic and hydrophilic organic contaminants in surface waters was recommended. |
| Department | 中国科学院饮用水科学与技术重点实验室; 环境水质学国家重点实验室 ; 中国科学院饮用水科学与技术重点实验室; 环境水质学国家重点实验室 |
| Keyword | PERFORMANCE REFERENCE COMPOUNDS ORGANIC CONTAMINANTS DIFFUSIVE GRADIENTS THIN-FILMS EXPOSURE POLLUTANTS HLB |
| Document Type | 期刊论文 |
| Identifier | https://ir.rcees.ac.cn/handle/311016/47890 |
| Collection | 中国科学院饮用水科学与技术重点实验室 |
| Corresponding Author | Zhou, Qingxiang |
| Affiliation | 1.China Univ Petr, State Key Lab Heavy Oil Proc, State Key Lab Petr Pollut Control, Beijing 102249, Peoples R China 2.Shenzhen Univ, Coll Chem & Environm Engn, Shenzhen Key Lab Environm Chem & Ecol Remediat, Shenzhen 518060, Peoples R China 3.Chinese Acad Sci, Res Ctr Ecoenvironm Sci, Key Lab Drinking Water Sci & Technol, Beijing 100085, Peoples R China 4.Chinese Acad Sci, Res Ctr Ecoenvironm Sci, State Key Lab Environm Aquat Chem, Beijing 100085, Peoples R China |
| Recommended Citation GB/T 7714 | Gao, Xiaozhong,Li, Juying,Xu, Yiping,et al. Passive sampling hydrophilic and hydrophobic bisphenol analogues using hydrophilic-lipophilic balance sorbent-embedded cellulose acetate membrane in surface waters[J]. SCIENCE OF THE TOTAL ENVIRONMENT,2022,839(0):156239. |
| APA | Gao, Xiaozhong,Li, Juying,Xu, Yiping,Zhou, Qingxiang,Ma, Mei,&Wang, Zijian.(2022).Passive sampling hydrophilic and hydrophobic bisphenol analogues using hydrophilic-lipophilic balance sorbent-embedded cellulose acetate membrane in surface waters.SCIENCE OF THE TOTAL ENVIRONMENT,839(0),156239. |
| MLA | Gao, Xiaozhong,et al."Passive sampling hydrophilic and hydrophobic bisphenol analogues using hydrophilic-lipophilic balance sorbent-embedded cellulose acetate membrane in surface waters".SCIENCE OF THE TOTAL ENVIRONMENT 839.0(2022):156239. |
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| Passive sampling hyd（2106KB） | 期刊论文 | 出版稿 | 开放获取 | CC BY-NC-SA | View Download | |
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