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Ultrathin Bi4O5Br2 nanosheets with surface oxygen vacancies and strong interaction with Bi2O2CO3 for highly efficient removal of water contaminants
Zhang, Lili; Wang, Zhiqiang; Li, Tong; Hu, Chun; Yang, Min
2022-04-14
Source PublicationENVIRONMENTAL SCIENCE-NANO
ISSN2051-8153
Volume9Issue:4Pages:1341-1352
AbstractUltrathin Bi4O5Br2 nanosheets with about a 10 nm thickness were synthesized by in situ intergrowth with Bi2O2CO3 sheets at room temperature. The degradation rates of organic pollutants on the catalyst were 28.1, 9.5, and 8.5 times higher than those on P25, N-TiO2 and 50 nm thick Bi4O5Br2 under a visible LED. The supreme catalytic activity was confirmed to be due to the significantly enhanced charge separation and transfer by surface oxygen vacancies on the ultrathin nanosheets, and the facilitated adsorption-degradation process at the solid-liquid micro-interface. The photogenerated electrons were demonstrated to be trapped on surface OVs to reduce surface adsorbed O-2 into O-2(-). Meanwhile, the photogenerated holes were effectively utilized to directly oxidize organic pollutants at the catalyst surface. FTIR, HPLC-Q-TOF-MS and IC analysis confirmed that diclofenac (DCF) was degraded at the catalyst surface through decarboxylation, dechloridation and C-N cleavage, and further mineralized in reaction solution. In addition, the developed catalyst can work at different pH values (5-10) and was stable after eight reaction cycles, showing good potential in practical application.
Department中国科学院饮用水科学与技术重点实验室 ; 中国科学院饮用水科学与技术重点实验室
KeywordPHOTOCATALYTIC DEGRADATION POLLUTANTS FACETS
Document Type期刊论文
Identifierhttps://ir.rcees.ac.cn/handle/311016/47914
Collection中国科学院饮用水科学与技术重点实验室
Corresponding AuthorHu, Chun
Affiliation1.Chinese Acad Sci, Res Ctr Ecoenvironm Sci, Key Lab Drinking Water Sci & Technol, Beijing 100085, Peoples R China
2.Guangzhou Univ, Inst Environm Res Greater Bay, Key Lab Water Qual & Conservat Pearl River Delta, Minist Educ, Guangzhou 510006, Peoples R China
Recommended Citation
GB/T 7714
Zhang, Lili,Wang, Zhiqiang,Li, Tong,et al. Ultrathin Bi4O5Br2 nanosheets with surface oxygen vacancies and strong interaction with Bi2O2CO3 for highly efficient removal of water contaminants[J]. ENVIRONMENTAL SCIENCE-NANO,2022,9(4):1341-1352.
APA Zhang, Lili,Wang, Zhiqiang,Li, Tong,Hu, Chun,&Yang, Min.(2022).Ultrathin Bi4O5Br2 nanosheets with surface oxygen vacancies and strong interaction with Bi2O2CO3 for highly efficient removal of water contaminants.ENVIRONMENTAL SCIENCE-NANO,9(4),1341-1352.
MLA Zhang, Lili,et al."Ultrathin Bi4O5Br2 nanosheets with surface oxygen vacancies and strong interaction with Bi2O2CO3 for highly efficient removal of water contaminants".ENVIRONMENTAL SCIENCE-NANO 9.4(2022):1341-1352.
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